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{{Chembox
{{Chembox
| ImageFile = Clark 2.svg
| ImageFile = Clark 2.svg
| ImageSize = 244
| ImageSize = 180
| ImageName = Structural formula of diphenylcyanoarsine
| ImageAlt = Structural formula of diphenylcyanoarsine
| ImageFile1 = Diphenylcyanoarsine-3D-spacefill.png
| ImageSize1 = 180
| ImageAlt1 = Space-filling model of diphenylcyanoarsine
| PIN = Diphenylarsinous cyanide
| PIN = Diphenylarsinous cyanide
| SystematicName = Diphenylarsanecarbonitrile
| SystematicName = Diphenylarsanecarbonitrile

Revision as of 23:26, 17 July 2012

Diphenylcyanoarsine
Structural formula of diphenylcyanoarsine
Space-filling model of diphenylcyanoarsine
Names
Preferred IUPAC name
Diphenylarsinous cyanide
Systematic IUPAC name
Diphenylarsanecarbonitrile
Other names
Clark 2

Diphenylarsinecarbonitrile
Diphenylarsine cyanide
Di(phenyl)arsanylformonitrile

Diphenylcyanoarsine
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.041.545 Edit this at Wikidata
EC Number
  • 245-716-6
MeSH Clark+2
  • InChI=1S/C13H10AsN/c15-11-14(12-7-3-1-4-8-12)13-9-5-2-6-10-13/h1-10H checkY
    Key: BDHNJKLLVSRGDK-UHFFFAOYSA-N checkY
  • InChI=1/C13H10AsN/c15-11-14(12-7-3-1-4-8-12)13-9-5-2-6-10-13/h1-10H
  • C1=CC=C(C=C1)[As](C#N)C2=CC=CC=C2
  • N#C[As](C1=CC=CC=C1)C1=CC=CC=C1
Properties
C13H10AsN
Molar mass 255.002920742 g mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Diphenylcyanoarsine, also called CLARK 2 (Cyanide-Arsenic Kampfstoff) by the Germans, was discovered in 1918 by Sturniolo and Bellinzoni[1] and shortly thereafter used like the related Clark 1 gas by the Germans for chemical warfare in the First World War. The substance forms colourless, garlic-smelling crystals and causes nausea, vomiting and headaches. It can subsequently lead to e.g. pulmonary oedema (fluid on the lungs).

See also

References

  1. ^ Sturniolo, G. und Bellinzoni , G. (1919); Boll. chim. pharm., 58, 409–410

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