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Importing Wikidata short description: "Group of chemical compounds" (Shortdesc helper) |
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{{Short description|Group of chemical compounds}} |
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{{importance}} |
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[[File:Anisoyl chloride isomers.svg|300px|thumb|[[Arene substitution patterns|Positional isomers]] of anisoyl chloride: ''ortho'' (2-methoxybenzoyl chloride), ''meta'' (3-methoxybenzoyl chloride), and ''para'' (4-methoxybenzoyl chloride)]] |
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{| class="toccolours" border="1" style="float: right; clear: right; margin: 0 0 1em 1em; border-collapse: collapse;" |
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! {{chembox header}} | Anisoyl chloride <!-- replace if not identical with the article name --> |
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| align="center" colspan="2" bgcolor="#ffffff" | [[Image:Anisoyl chloride.jpg|200px|Anisoyl chloride]] <!-- replace if not identical with the pagename --> |
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! {{chembox header}} | General |
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| [[IUPAC nomenclature|Systematic name]] |
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| ? <!-- e.g. Iron(II) chloride --> |
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| Other names |
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| ? <!-- e.g. Ferrous chloride etc, + linked mineral names --> |
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|- |
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| [[Chemical formula|Molecular formula]] |
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| ? <!-- e.g. Na<sub>2</sub>CO<sub>3</sub> --> |
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|- |
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| [[Simplified molecular input line entry specification|SMILES]] <!-- mostly for organic compounds, omit otherwise --> |
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| ? |
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| [[Molar mass]] |
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| ?.?? g/mol |
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| Appearance |
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| ? <!-- e.g. pale yellow solid, [[hygroscopic]] --> |
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| [[CAS registry number|CAS number]] |
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| [?-?-?] |
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! {{chembox header}} | Properties |
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| [[Density]] and [[Phase (matter)|phase]] |
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| ? g/cm³, ? <!-- ? g/cm³, solid / ? g/ml, liquid / ? g/l, gas --> |
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| [[Solubility]] in [[Water (molecule)|water]] |
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| ? g/100 ml (?°C) <!-- at least put miscible with, not soluble in --> |
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|- |
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<!-- | Other solvents e.g. [[ethanol]], [[acetone]] --> |
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<!-- | solubility info on other solvents --> |
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| [[Melting point]] |
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| ?°C (? K) <!-- (mention any decomposition) --> |
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| [[Boiling point]] |
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| ?°C (? K) |
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| [[Acid dissociation constant|Acidity]] (p''K''<sub>a</sub>) <!-- omit if not an acid or a base. If several values, be clear --> |
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| ? |
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| [[Acid dissociation constant|Basicity]] (p''K''<sub>b</sub>) <!-- omit if not a base. If several values, be clear --> |
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| ? |
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| [[Specific rotation|Chiral rotation <nowiki>[α]</nowiki><sub>D</sub>]] <!-- (Only include this for chiral compounds, indicate direction/enantiomer combo if known) --> |
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| ?° |
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| [[Viscosity]] |
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| ? [[Poise|cP]] at ?°C <!-- Liquids only, omit if data unavailable. You may use [[Pascal second|Pa.s]] if you prefer --> |
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! {{chembox header}} | Structure |
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|- |
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| [[Orbital hybridisation#Molecule shape|Molecular shape]] <!-- for simple covalent molecules (omit for most large molecules, ionics and complexes) --> |
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| ? <!-- e.g. trigonal bipyramidal --> |
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| [[Coordination geometry|Coordination<br />geometry]] <!-- for a metal complex or an ionic crystal, otherwise omit --> |
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| ? <!-- e.g. trigonal bipyramidal --> |
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| [[Crystal structure]] <!-- omit if not a solid --> |
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| ? <!-- e.g. [[triclinic]], [[monoclinic]], [[orthorhombic]], [[hexagonal]], [[rhombohedral|trigonal]], [[tetragonal]], [[cubic]], and mention "close packed" or similar. You may also cite what class it belongs to, e.g. [[Cadmium_chloride#Crystal_structure|CdCl<sub>2</sub>]] --> |
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|- |
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| [[Dipole#Molecular dipoles|Dipole moment]] |
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| ? [[Debye|D]] |
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! {{chembox header}} | Hazards <!-- Summary only- MSDS entry provides more complete information --> |
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|- |
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| [[Material safety data sheet|MSDS]] |
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| [[Anisoyl chloride (data page)#Material Safety Data Sheet|External MSDS]] <!-- please replace with proper link--> |
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| Main [[Worker safety and health|hazard]]s |
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| ? <!-- e.g. highly toxic, explosive, flammable, corrosive --> |
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| [[NFPA 704]] |
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| <!-- {{nfpa|4|4 ox|4}} These are set on "very dangerous" as default- adjust according to actual values --> |
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| [[Flash point]] |
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| ?°C |
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| [[Risk and Safety Statements|R/S statement]] |
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| [[List of R-phrases|R]]: ? <br /> [[List of S-phrases|S]]: ? |
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| [[RTECS]] number |
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| ? |
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! {{chembox header}} | [[Anisoyl chloride (data page)|Supplementary data page]] |
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| [[Anisoyl chloride (data page)#Structure and properties|Structure and<br />properties]] |
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| [[Refractive index|''n'']], [[Dielectric constant|ε<sub>r</sub>]], etc. |
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| [[Anisoyl chloride (data page)#Thermodynamic properties|Thermodynamic<br />data]] |
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| Phase behaviour<br />Solid, liquid, gas |
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| [[Anisoyl chloride (data page)#Spectral data|Spectral data]] |
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| [[UV/VIS spectroscopy|UV]], [[Infrared spectroscopy|IR]], [[nuclear magnetic resonance spectroscopy|NMR]], [[Mass spectrometry|MS]] |
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! {{chembox header}} | Related compounds |
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|- |
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| Other [[Ion|anion]]s <!-- please omit if not applicable --> |
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| ? <!-- Put in related anions e.g, iron(II) fluoride & iron(II) bromide if compound is iron(II) chloride --> |
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|- |
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| Other [[Ion|cation]]s <!-- please omit if not applicable --> |
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| ? <!-- Put in other oxidation states of same element e.g. [[iron(III) chloride]], also for related metals such as [[manganese(II) chloride]], [[cobalt(II) chloride]], ruthenium(III) chloride--> |
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|- |
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| Related [[?]] <!-- PLEASE INSERT FUNCTIONAL GROUP (e.g. [[aldehyde]]) FOR ORGANICS, please omit if not applicable --> |
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| ? <!-- Insert related organics e.g. on formaldehyde page put [[acetaldehyde]] --> |
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|- |
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| Related compounds |
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<!-- A miscellaneous heading - use for covalent inorganics; e.g. for PCl<sub>3</sub> you would list PCl<sub>5</sub>, POCl<sub>3</sub>, PF<sub>3</sub>, PBr<sub>3</sub>, NCl<sub>3</sub> and AsCl<sub>3</sub>. |
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Please omit if not applicable --> |
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| ? |
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| {{chembox header}} | <small>Except where noted otherwise, data are given for<br /> materials in their [[standard state|standard state (at 25°C, 100 kPa)]]<br />[[wikipedia:Chemical infobox|Infobox disclaimer and references]]</small> |
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'''Anisoyl chloride''' (also called '''methoxybenzoyl chloride''') is an [[acyl halide]], specifically an [[aromatic]] acyl chloride, and may be formed from [[anisic acid]] by replacing a [[hydroxyl]] group of the [[carboxylic acid]] with a [[chloride]] group. There are three [[isomers]]: the ''ortho-'', ''meta-'', and ''para-'' forms. Their structures differ in the [[arene substitution pattern]]—the location of the [[methoxy]] group on the ring as compared to the acyl halide. |
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{{-}} |
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==External sources== |
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==References== |
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* [http://webbook.nist.gov/cgi/cbook.cgi?ID=C100072 National Institute of Standards and Technology (NIST) reference data for anisoyl chloride] |
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* [https://echa.europa.eu/substance-information/-/substanceinfo/100.002.561] |
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{{ |
{{aromatic-stub}} |
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[[Category:Benzene derivatives]] |
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[[Category:Aromatic compounds]] |
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[[Category:Acyl chlorides]] |
[[Category:Acyl chlorides]] |
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[[Category:Phenol ethers]] |
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{{aromatic-stub}} |
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Latest revision as of 20:59, 2 October 2021
Anisoyl chloride (also called methoxybenzoyl chloride) is an acyl halide, specifically an aromatic acyl chloride, and may be formed from anisic acid by replacing a hydroxyl group of the carboxylic acid with a chloride group. There are three isomers: the ortho-, meta-, and para- forms. Their structures differ in the arene substitution pattern—the location of the methoxy group on the ring as compared to the acyl halide.