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Updating {{chembox}} (no changed fields - added verified revid - updated 'UNII_Ref', 'ChemSpiderID_Ref', 'StdInChI_Ref', 'StdInChIKey_Ref') per Chem/Drugbox validation (report [[Wikipedia_talk:Wi
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[[Category:Triarylmethane dyes]]
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[[Category:Salicylates]]
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[[Category:Ammonium compounds]]


[[de:Aluminon]]
[[de:Aluminon]]

Revision as of 05:33, 5 March 2011

Aluminon
Names
Other names
ammonium aurin-tricarboxylate; 5-[(3-carboxy-4-hydroxyphenyl)(3-carboxy-4-oxo-2,5-cyclohexadien-ylidene)methyl]-2-hydroxybenzoic acid triammonium salt
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.008.473 Edit this at Wikidata
  • InChI=1S/C22H14O9.3H3N/c23-16-4-1-10(7-13(16)20(26)27)19(11-2-5-17(24)14(8-11)21(28)29)12-3-6-18(25)15(9-12)22(30)31;;;/h1-9,23-24H,(H,26,27)(H,28,29)(H,30,31);3*1H3 checkY
    Key: AIPNSHNRCQOTRI-UHFFFAOYSA-N checkY
  • InChI=1/C22H14O9.3H3N/c23-16-4-1-10(7-13(16)20(26)27)19(11-2-5-17(24)14(8-11)21(28)29)12-3-6-18(25)15(9-12)22(30)31;;;/h1-9,23-24H,(H,26,27)(H,28,29)(H,30,31);3*1H3
    Key: AIPNSHNRCQOTRI-UHFFFAOYAI
  • O=C([O-])\C1=C\C(\C=C/C1=O)=C(\c2ccc(O)c(C([O-])=O)c2)c3ccc(O)c(C([O-])=O)c3.[NH4+].[NH4+].[NH4+]
Properties
C22H23N3O9
Molar mass 473.43 g/mol
Appearance yellow-brown crystals, red in aqueous solution
Solubility in other solvents freely soluble in H2O
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Aluminon, the triammonium salt of aurintricarboxylic acid, is a dye commonly used to detect the presence of the aluminium ion in an aqueous solution. In addition to its use in qualitative inorganic analysis, aluminon has applications in pharyngeal aerosols. It forms brilliantly colored lake pigments with aluminum, chromium, iron, and beryllium.

Aluminon is prepared by reacting sodium nitrite with salicylic acid, adding formaldehyde, then treating with ammonia.[1]

See also

References

  1. ^ Merck Index, 13th Ed.

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