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| OtherNames = Methyl propenyl sulfide<br /> |
| OtherNames = Methyl propenyl sulfide<br /> |
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3-Methylthio-1-propene |
3-Methylthio-1-propene |
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|Section1={{Chembox Identifiers |
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| CASNo_Ref = {{cascite|changed|??}} |
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| CASNo = 10152-76-8 |
| CASNo = 10152-76-8 |
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| PubChem = 66282 |
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| PubChem_Ref = {{pubchemcite|correct|pubchem}} |
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| EINECS = 233-422-0 |
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| UNNumber = 1993 |
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| UNNumber = 1993 |
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| RTECS = UD1015000 |
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| SMILES = CSCC=C |
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| SMILES = CSCC=C |
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|Section2={{Chembox Properties |
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| C=4 | H=8 | S=1 |
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| Odor = Garlic |
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| S = 1 |
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| ExactMass = 88.034670946 g mol<sup>−1</sup> |
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| Odor = Garlic |
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|Section3={{Chembox Hazards |
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| GHSPictograms = {{GHS flame}} |
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| GHSSignalWord = '''DANGER''' |
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| HPhrases = {{H-phrases|225}} |
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| PPhrases = {{P-phrases|210}} |
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| EUClass = {{Hazchem F}} |
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| RPhrases = {{R11}} |
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| SPhrases = {{S16}}, {{S29}}, {{S33}} |
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| FlashPtC = 18.0 |
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Revision as of 11:25, 24 June 2015
Names | |
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Preferred IUPAC name
3-Methylsulfanylprop-1-ene | |
Other names
Methyl propenyl sulfide
3-Methylthio-1-propene | |
Identifiers | |
3D model (JSmol)
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ChemSpider | |
ECHA InfoCard | 100.030.371 |
EC Number |
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MeSH | allyl+methyl+sulfide |
PubChem CID
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RTECS number |
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UN number | 1993 |
CompTox Dashboard (EPA)
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Properties | |
C4H8S | |
Molar mass | 88.17 g·mol−1 |
Odor | Garlic |
Density | 0.803 g cm−3 |
Boiling point | 92 °C; 197 °F; 365 K |
Hazards | |
GHS labelling: | |
Danger | |
H225 | |
P210 | |
Flash point | 18.0 °C (64.4 °F; 291.1 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Allyl methyl sulfide (AMS) is an organosulfur compound with the chemical formula CH2=CHCH2SCH3. The molecule features two functional groups, an allyl (CH2=CHCH2) and a sulfide. It is a colourless liquid with a strong odor characteristic of alkyl sulfides. It is a metabolite of garlic, and "garlic breath" is attributed to its presence.[1]
It is prepared by the reaction of allyl chloride with sodium hydroxide and methanethiol.
- CH2=CHCH2Cl + NaOH(aq) + CH3SH → CH2=CHCH2SCH3 + NaCl + H2O