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Script assisted update of identifiers from ChemSpider, CommonChemistry and FDA for the Chem/Drugbox validation project - Updated: StdInChI StdInChIKey.
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Updating {{chembox}} (no changed fields - added verified revid - updated 'UNII_Ref', 'ChemSpiderID_Ref', 'StdInChI_Ref', 'StdInChIKey_Ref') per Chem/Drugbox validation (report [[Wikipedia_talk:Wi
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{{Unreferenced stub|auto=yes|date=December 2009}}
{{Unreferenced stub|auto=yes|date=December 2009}}
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|ImageFile=Ammonium-chlorate-3D-balls.png
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|OtherNames=
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|Section1={{Chembox Identifiers
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 55411
| ChemSpiderID = 55411
| InChI = 1/ClHO3.H3N/c2-1(3)4;/h(H,2,3,4);1H3
| InChI = 1/ClHO3.H3N/c2-1(3)4;/h(H,2,3,4);1H3
| InChIKey = KHPLPBHMTCTCHA-UHFFFAOYAQ
| InChIKey = KHPLPBHMTCTCHA-UHFFFAOYAQ
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/ClHO3.H3N/c2-1(3)4;/h(H,2,3,4);1H3
| StdInChI = 1S/ClHO3.H3N/c2-1(3)4;/h(H,2,3,4);1H3
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = KHPLPBHMTCTCHA-UHFFFAOYSA-N
| StdInChIKey = KHPLPBHMTCTCHA-UHFFFAOYSA-N
| CASNo=10192-29-7
| CASNo=10192-29-7

Revision as of 12:46, 29 November 2010

Ammonium chlorate
Ammonium chlorate
Names
IUPAC name
Ammonium chlorate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.413 Edit this at Wikidata
  • InChI=1S/ClHO3.H3N/c2-1(3)4;/h(H,2,3,4);1H3 checkY
    Key: KHPLPBHMTCTCHA-UHFFFAOYSA-N checkY
  • InChI=1/ClHO3.H3N/c2-1(3)4;/h(H,2,3,4);1H3
    Key: KHPLPBHMTCTCHA-UHFFFAOYAQ
  • O=Cl(=O)O.N
Properties
ClH4NO3
Molar mass 101.49 g·mol−1
Appearance small colorless crystals
Density 2.42 g/cm3
Melting point 380 °C (decomp.)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
strong oxidant, decomposes when heated
Related compounds
Other anions
Ammonium chloride
Ammonium perchlorate
Other cations
Barium chlorate
Potassium chlorate
Sodium chlorate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Ammonium chlorate is an inorganic compound with the formula NH4ClO3.

It is obtained by neutralizing chloric acid with either ammonia or ammonium carbonate, or by precipitating barium, strontium or calcium chlorates with ammonium carbonate or ammonium sulfate, producing the respective carbonate or sulfate precipitate and an ammonium chlorate solution. Ammonium chlorate crystallizes in small needles, readily soluble in water.

On heating, ammonium chlorate decomposes at about 102 °C, with liberation of nitrogen, chlorine and oxygen. It is soluble in dilute aqueous alcohol, but insoluble in strong alcohol. This compound is a strong oxidizer and should never be stored with flammable materials.

Ammonium chlorate is a very unstable oxidizer and will decompose, sometimes violently, at room temperature. This results from the mixture of the reducing ammonium cation and the oxidizing chlorate anion. It will explode when exposed to sunlight for a few minutes. Even solutions are known to be unstable. Because of the dangerous nature of this salt it should only be kept in solution when needed, and never be allowed to crystallize.


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