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Script assisted update of identifiers from ChemSpider, CommonChemistry and FDA for the Chem/Drugbox validation project - Updated: StdInChI StdInChIKey.
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Updating {{chembox}} (no changed fields - added verified revid - updated 'UNII_Ref', 'ChemSpiderID_Ref', 'StdInChI_Ref', 'StdInChIKey_Ref') per Chem/Drugbox validation (report [[Wikipedia_talk:Wi
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| verifiedrevid = 399507668
| ImageFile = Ammelide.png
| ImageFile = Ammelide.png
| ImageSize = 150px
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| Section1 = {{Chembox Identifiers
| Section1 = {{Chembox Identifiers
| Abbreviations =
| Abbreviations =
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 12064
| ChemSpiderID = 12064
| InChIKey = YSKUZVBSHIWEFK-UHFFFAOYAA
| InChIKey = YSKUZVBSHIWEFK-UHFFFAOYAA
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/C3H4N4O2/c4-1-5-2(8)7-3(9)6-1/h(H4,4,5,6,7,8,9)
| StdInChI = 1S/C3H4N4O2/c4-1-5-2(8)7-3(9)6-1/h(H4,4,5,6,7,8,9)
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = YSKUZVBSHIWEFK-UHFFFAOYSA-N
| StdInChIKey = YSKUZVBSHIWEFK-UHFFFAOYSA-N
| CASNo = 645-93-2
| CASNo = 645-93-2

Revision as of 12:40, 29 November 2010

Ammelide
Structural formula
Ball-and-stick model
Names
IUPAC name
6-Amino-2,4-Dihydroxy-l,3,5-Triazine
Other names
Ammelid, 2-Amino-1,3,5-triazine-4,6-dione, 2-Amino-4,6-dihydroxy-s-triazine
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.010.416 Edit this at Wikidata
  • InChI=1S/C3H4N4O2/c4-1-5-2(8)7-3(9)6-1/h(H4,4,5,6,7,8,9) checkY
    Key: YSKUZVBSHIWEFK-UHFFFAOYSA-N checkY
  • InChI=1/C3H4N4O2/c4-1-5-2(8)7-3(9)6-1/h(H4,4,5,6,7,8,9)
    Key: YSKUZVBSHIWEFK-UHFFFAOYAA
  • O=C1NC(=N/C(=O)N1)\N
Properties
C3H4N4O2
Molar mass 128.09 g/mol
Appearance white powder
insoluble
Solubility soluble in concentrated mineral acids, alkalies and ammonia
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Ammelide (6-Amino-2,4-Dihydroxy-1,3,5-Triazine) is a triazine and the hydrolysis product of ammeline.

Synthesis

Ammelide can be obtained by heating dicyandiamide with aqueous ammonia at 160-170°C. It can also be synthezised by heating melam with concentrated sulfuric acid for a short time at 190°C.

Chemical property

Ammelide forms salts with both acids (hydrochloric acid, nitric acid, sulfuric acid)and bases (sodium hydroxide, ammonium, calcium hydroxide).

Ammelide decomposes at 170oC with water to form carbon dioxide and ammonia. It can be converted into cyanuric acid by oxidizing agents (e.g. potassium permanganate) or by boiling with acids or alkalies.

References

  • B. Bann and S.A. Miller, "Melamines and derivatives of melamine", Chemical Reviews, vol.58, p131-172 (1958).

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