Terpene

Authors
Yan Gao, Peter Lee, Philip Coppens, MA Subramania, AW Sleight
Publication date
1988/8/19
Journal
Science
Volume
241
Issue
4868
Pages
954-956
Publisher
American Association for the Advancement of Science
Description
The incommensurate modulation evident in the diffraction pattern of the superconductor Bi2Sr3-xCaxCu2O8+y consists of almost sinusoidally varying displacements of up to 0.4 Å of the Bi and Sr atoms in the a- and c-directions of the unit cell, and of up to 0.3 Å of the Cu atoms in the c direction only. Thus, a newly discovered feature of the Bi2Sr3-xCaxCu2O8+y structure is sizable Cu displacement, which is related to static wave formation in the Cu-O sheets. Reported thermal parameters give evidence that similar distortions occur on cooling of the thallium-containing superconductors.
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