Titanium | |||||||||||||||||||||||||||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Pronunciation | |||||||||||||||||||||||||||||||||||||||||
Appearance | silvery grey-white metallic | ||||||||||||||||||||||||||||||||||||||||
Standard atomic weight Ar°(Ti) | |||||||||||||||||||||||||||||||||||||||||
Titanium in the periodic table | |||||||||||||||||||||||||||||||||||||||||
| |||||||||||||||||||||||||||||||||||||||||
Atomic number (Z) | 22 | ||||||||||||||||||||||||||||||||||||||||
Group | group 4 | ||||||||||||||||||||||||||||||||||||||||
Period | period 4 | ||||||||||||||||||||||||||||||||||||||||
Block | d-block | ||||||||||||||||||||||||||||||||||||||||
Electron configuration | [Ar] 3d2 4s2 | ||||||||||||||||||||||||||||||||||||||||
Electrons per shell | 2, 8, 10, 2 | ||||||||||||||||||||||||||||||||||||||||
Physical properties | |||||||||||||||||||||||||||||||||||||||||
Phase at STP | solid | ||||||||||||||||||||||||||||||||||||||||
Melting point | 1941 K (1668 °C, 3034 °F) | ||||||||||||||||||||||||||||||||||||||||
Boiling point | 3560 K (3287 °C, 5949 °F) | ||||||||||||||||||||||||||||||||||||||||
Density (at 20° C) | 4.502 g/cm3 [4] | ||||||||||||||||||||||||||||||||||||||||
when liquid (at m.p.) | 4.11 g/cm3 | ||||||||||||||||||||||||||||||||||||||||
Heat of fusion | 14.15 kJ/mol | ||||||||||||||||||||||||||||||||||||||||
Heat of vaporization | 425 kJ/mol | ||||||||||||||||||||||||||||||||||||||||
Molar heat capacity | 25.060 J/(mol·K) | ||||||||||||||||||||||||||||||||||||||||
Vapor pressure
| |||||||||||||||||||||||||||||||||||||||||
Atomic properties | |||||||||||||||||||||||||||||||||||||||||
Oxidation states | −2, −1, 0,[5] +1, +2, +3, +4[6] (an amphoteric oxide) | ||||||||||||||||||||||||||||||||||||||||
Electronegativity | Pauling scale: 1.54 | ||||||||||||||||||||||||||||||||||||||||
Ionization energies |
| ||||||||||||||||||||||||||||||||||||||||
Atomic radius | empirical: 147 pm | ||||||||||||||||||||||||||||||||||||||||
Covalent radius | 160±8 pm | ||||||||||||||||||||||||||||||||||||||||
![]() | |||||||||||||||||||||||||||||||||||||||||
Other properties | |||||||||||||||||||||||||||||||||||||||||
Natural occurrence | primordial | ||||||||||||||||||||||||||||||||||||||||
Crystal structure | hexagonal close-packed (hcp) (hP2) | ||||||||||||||||||||||||||||||||||||||||
Lattice constants | a = 295.05 pm c = 468.33 pm (at 20 °C)[4] | ||||||||||||||||||||||||||||||||||||||||
Thermal expansion | 9.68×10−6/K (at 20 °C)[a] | ||||||||||||||||||||||||||||||||||||||||
Thermal conductivity | 21.9 W/(m⋅K) | ||||||||||||||||||||||||||||||||||||||||
Electrical resistivity | 420 nΩ⋅m (at 20 °C) | ||||||||||||||||||||||||||||||||||||||||
Magnetic ordering | paramagnetic | ||||||||||||||||||||||||||||||||||||||||
Molar magnetic susceptibility | +153.0×10−6 cm3/mol (293 K)[7] | ||||||||||||||||||||||||||||||||||||||||
Young's modulus | 116 GPa | ||||||||||||||||||||||||||||||||||||||||
Shear modulus | 44 GPa | ||||||||||||||||||||||||||||||||||||||||
Bulk modulus | 110 GPa | ||||||||||||||||||||||||||||||||||||||||
Speed of sound thin rod | 5090 m/s (at r.t.) | ||||||||||||||||||||||||||||||||||||||||
Poisson ratio | 0.32 | ||||||||||||||||||||||||||||||||||||||||
Mohs hardness | 6.0 | ||||||||||||||||||||||||||||||||||||||||
Vickers hardness | 830–3420 MPa | ||||||||||||||||||||||||||||||||||||||||
Brinell hardness | 716–2770 MPa | ||||||||||||||||||||||||||||||||||||||||
CAS Number | 7440-32-6 | ||||||||||||||||||||||||||||||||||||||||
History | |||||||||||||||||||||||||||||||||||||||||
Discovery | William Gregor (1791) | ||||||||||||||||||||||||||||||||||||||||
First isolation | Jöns Jakob Berzelius (1825) | ||||||||||||||||||||||||||||||||||||||||
Named by | Martin Heinrich Klaproth (1795) | ||||||||||||||||||||||||||||||||||||||||
Isotopes of titanium | |||||||||||||||||||||||||||||||||||||||||
| |||||||||||||||||||||||||||||||||||||||||
Titanium is a chemical element; it has symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in sea water, aqua regia, and chlorine.
Titanium was discovered in Cornwall, Great Britain, by William Gregor in 1791 and was named by Martin Heinrich Klaproth after the Titans of Greek mythology. The element occurs within a number of minerals, principally rutile and ilmenite, which are widely distributed in the Earth's crust and lithosphere; it is found in almost all living things, as well as bodies of water, rocks, and soils.[9] The metal is extracted from its principal mineral ores by the Kroll and Hunter processes.[10] The most common compound, titanium dioxide, is a popular photocatalyst and is used in the manufacture of white pigments.[11] Other compounds include titanium tetrachloride (TiCl4), a component of smoke screens and catalysts; and titanium trichloride (TiCl3), which is used as a catalyst in the production of polypropylene.[9]
Titanium can be alloyed with iron, aluminium, vanadium, and molybdenum, among other elements. The resulting titanium alloys are strong, lightweight, and versatile, with applications including aerospace (jet engines, missiles, and spacecraft), military, industrial processes (chemicals and petrochemicals, desalination plants, pulp, and paper), automotive, agriculture (farming), sporting goods, jewelry, and consumer electronics.[9] Titanium is also considered one of the most biocompatible metals, leading to a range of medical applications including prostheses, orthopedic implants, dental implants, and surgical instruments.[12]
The two most useful properties of the metal are corrosion resistance and strength-to-density ratio, the highest of any metallic element.[13] In its unalloyed condition, titanium is as strong as some steels, but less dense.[14] There are two allotropic forms[15] and five naturally occurring isotopes of this element, 46Ti through 50Ti, with 48Ti being the most abundant (73.8%).[16]
Characteristics
Physical properties
As a metal, titanium is recognized for its high strength-to-weight ratio.[15] It is a strong metal with low density that is quite ductile (especially in an oxygen-free environment),[9] lustrous, and metallic-white in color.[17] Due to its relatively high melting point (1,668 °C or 3,034 °F) it has sometimes been described as a refractory metal, but this is not the case.[18] It is paramagnetic and has fairly low electrical and thermal conductivity compared to other metals.[9] Titanium is superconducting when cooled below its critical temperature of 0.49 K.[19][20]
Commercially pure (99.2% pure) grades of titanium have ultimate tensile strength of about 434 MPa (63,000 psi), equal to that of common, low-grade steel alloys, but are less dense. Titanium is 60% denser than aluminium, but more than twice as strong[14] as the most commonly used 6061-T6 aluminium alloy. Certain titanium alloys (e.g., Beta C) achieve tensile strengths of over 1,400 MPa (200,000 psi).[21] However, titanium loses strength when heated above 430 °C (806 °F).[22]
Titanium is not as hard as some grades of heat-treated steel; it is non-magnetic and a poor conductor of heat and electricity. Machining requires precautions, because the material can gall unless sharp tools and proper cooling methods are used. Like steel structures, those made from titanium have a fatigue limit that guarantees longevity in some applications.[17]
The metal is a dimorphic allotrope of a hexagonal α form that changes into a body-centered cubic (lattice) β form at 882 °C (1,620 °F).[22] The specific heat of the α form increases dramatically as it is heated to this transition temperature but then falls and remains fairly constant for the β form regardless of temperature.[22]
Chemical properties
![](https://upload.wikimedia.org/wikipedia/commons/thumb/8/8a/Titanium_in_water_Pourbaix_diagram.png/220px-Titanium_in_water_Pourbaix_diagram.png)
Like aluminium and magnesium, the surface of titanium metal and its alloys oxidize immediately upon exposure to air to form a thin non-porous passivation layer that protects the bulk metal from further oxidation or corrosion.[9] When it first forms, this protective layer is only 1–2 nm thick but it continues to grow slowly, reaching a thickness of 25 nm in four years.[24] This layer gives titanium excellent resistance to corrosion against oxidizing acids, but it will dissolve in dilute hydrofluoric acid, hot hydrochloric acid, and hot sulfuric acid.
Titanium is capable of withstanding attack by dilute sulfuric and hydrochloric acids at room temperature, chloride solutions, and most organic acids.[10] However, titanium is corroded by concentrated acids.[25] Titanium is a very reactive metal that burns in normal air at lower temperatures than the melting point. Melting is possible only in an inert atmosphere or vacuum. At 550 °C (1,022 °F), it combines with chlorine.[10] It also reacts with the other halogens and absorbs hydrogen.[11]
Titanium readily reacts with oxygen at 1,200 °C (2,190 °F) in air, and at 610 °C (1,130 °F) in pure oxygen, forming titanium dioxide.[15] Titanium is one of the few elements that burns in pure nitrogen gas, reacting at 800 °C (1,470 °F) to form titanium nitride, which causes embrittlement.[26] Because of its high reactivity with oxygen, nitrogen, and many other gases, titanium that is evaporated from filaments is the basis for titanium sublimation pumps, in which titanium serves as a scavenger for these gases by chemically binding to them. Such pumps inexpensively produce extremely low pressures in ultra-high vacuum systems.
Occurrence
Titanium is the ninth-most abundant element in Earth's crust (0.63% by mass)[27] and the seventh-most abundant metal. It is present as oxides in most igneous rocks, in sediments derived from them, in living things, and natural bodies of water.[9][10] Of the 801 types of igneous rocks analyzed by the United States Geological Survey, 784 contained titanium. Its proportion in soils is approximately 0.5–1.5%.[27]
Common titanium-containing minerals are anatase, brookite, ilmenite, perovskite, rutile, and titanite (sphene).[24] Akaogiite is an extremely rare mineral consisting of titanium dioxide. Of these minerals, only rutile and ilmenite have economic importance, yet even they are difficult to find in high concentrations. About 6.0 and 0.7 million tonnes of those minerals were mined in 2011, respectively.[28] Significant titanium-bearing ilmenite deposits exist in Australia, Canada, China, India, Mozambique, New Zealand, Norway, Sierra Leone, South Africa, and Ukraine.[24] About 210,000 tonnes of titanium metal sponge were produced in 2020, mostly in China (110,000 t), Japan (50,000 t), Russia (33,000 t) and Kazakhstan (15,000 t). Total reserves of anatase, ilmenite, and rutile are estimated to exceed 2 billion tonnes.[28]
Country | thousand tonnes |
% of total |
---|---|---|
China | 3,830 | 33.1 |
Australia | 1,513 | 13.1 |
Mozambique | 1,070 | 9.3 |
Canada | 1,030 | 8.9 |
South Africa | 743 | 6.4 |
Kenya | 562 | 4.9 |
India | 510 | 4.4 |
Senegal | 502 | 4.3 |
Ukraine | 492 | 4.3 |
World | 11,563 | 100 |
The concentration of titanium is about 4 picomolar in the ocean. At 100 °C, the concentration of titanium in water is estimated to be less than 10−7 M at pH 7. The identity of titanium species in aqueous solution remains unknown because of its low solubility and the lack of sensitive spectroscopic methods, although only the 4+ oxidation state is stable in air. No evidence exists for a biological role, although rare organisms are known to accumulate high concentrations of titanium.[29]
Titanium is contained in meteorites, and it has been detected in the Sun and in M-type stars[10] (the coolest type) with a surface temperature of 3,200 °C (5,790 °F).[30] Rocks brought back from the Moon during the Apollo 17 mission are composed of 12.1% TiO2.[10] Native titanium (pure metallic) is very rare.[31]
Isotopes
Naturally occurring titanium is composed of five stable isotopes: 46Ti, 47Ti, 48Ti, 49Ti, and 50Ti, with 48Ti being the most abundant (73.8% natural abundance). At least 21 radioisotopes have been characterized, the most stable of which are 44Ti with a half-life of 63 years; 45Ti, 184.8 minutes; 51Ti, 5.76 minutes; and 52Ti, 1.7 minutes. All other radioactive isotopes have half-lives less than 33 seconds, with the majority less than half a second.[16]
The isotopes of titanium range in atomic weight from 39.002 u (39Ti) to 63.999 u (64Ti).[32] The primary decay mode for isotopes lighter than 46Ti is positron emission (with the exception of 44Ti which undergoes electron capture), leading to isotopes of scandium, and the primary mode for isotopes heavier than 50Ti is beta emission, leading to isotopes of vanadium.[16]
Titanium becomes radioactive upon bombardment with deuterons, emitting mainly positrons and hard gamma rays.[10]
Compounds
![A steel colored twist drill bit with the spiral groove colored in a golden shade.](https://upload.wikimedia.org/wikipedia/commons/thumb/2/2b/Titanium_nitride_coating.jpg/60px-Titanium_nitride_coating.jpg)
The +4 oxidation state dominates titanium chemistry,[33] but compounds in the +3 oxidation state are also numerous.[34] Commonly, titanium adopts an octahedral coordination geometry in its complexes,[35][36] but tetrahedral TiCl4 is a notable exception. Because of its high oxidation state, titanium(IV) compounds exhibit a high degree of covalent bonding.[33]
Oxides, sulfides, and alkoxides
The most important oxide is TiO2, which exists in three important polymorphs; anatase, brookite, and rutile. All three are white diamagnetic solids, although mineral samples can appear dark (see rutile). They adopt polymeric structures in which Ti is surrounded by six oxide ligands that link to other Ti centers.[37]
The term titanates usually refers to titanium(IV) compounds, as represented by barium titanate (BaTiO3). With a perovskite structure, this material exhibits piezoelectric properties and is used as a transducer in the interconversion of sound and electricity.[15] Many minerals are titanates, such as ilmenite (FeTiO3). Star sapphires and rubies get their asterism (star-forming shine) from the presence of titanium dioxide impurities.[24]
A variety of reduced oxides (suboxides) of titanium are known, mainly reduced stoichiometries of titanium dioxide obtained by atmospheric plasma spraying. Ti3O5, described as a Ti(IV)-Ti(III) species, is a purple semiconductor produced by reduction of TiO2 with hydrogen at high temperatures,[38] and is used industrially when surfaces need to be vapor-coated with titanium dioxide: it evaporates as pure TiO, whereas TiO2 evaporates as a mixture of oxides and deposits coatings with variable refractive index.[39] Also known is Ti2O3, with the corundum structure, and TiO, with the rock salt structure, although often nonstoichiometric.[40]
The alkoxides of titanium(IV), prepared by treating TiCl4 with alcohols, are colorless compounds that convert to the dioxide on reaction with water. They are industrially useful for depositing solid TiO2 via the sol-gel process. Titanium isopropoxide is used in the synthesis of chiral organic compounds via the Sharpless epoxidation.[41]
Titanium forms a variety of sulfides, but only TiS2 has attracted significant interest. It adopts a layered structure and was used as a cathode in the development of lithium batteries. Because Ti(IV) is a "hard cation", the sulfides of titanium are unstable and tend to hydrolyze to the oxide with release of hydrogen sulfide.[42]
Nitrides and carbides
Titanium nitride (TiN) is a refractory solid exhibiting extreme hardness, thermal/electrical conductivity, and a high melting point.[43] TiN has a hardness equivalent to sapphire and carborundum (9.0 on the Mohs scale),[44] and is often used to coat cutting tools, such as drill bits.[45] It is also used as a gold-colored decorative finish and as a barrier layer in semiconductor fabrication.[46] Titanium carbide (TiC), which is also very hard, is found in cutting tools and coatings.[47]
Halides
![](https://upload.wikimedia.org/wikipedia/commons/thumb/c/cd/TiCl3.jpg/90px-TiCl3.jpg)
Titanium tetrachloride (titanium(IV) chloride, TiCl4[48]) is a colorless volatile liquid (commercial samples are yellowish) that, in air, hydrolyzes with spectacular emission of white clouds. Via the Kroll process, TiCl4 is used in the conversion of titanium ores to titanium metal. Titanium tetrachloride is also used to make titanium dioxide, e.g., for use in white paint.[49] It is widely used in organic chemistry as a Lewis acid, for example in the Mukaiyama aldol condensation.[50] In the van Arkel–de Boer process, titanium tetraiodide (TiI4) is generated in the production of high purity titanium metal.[51]
Titanium(III) and titanium(II) also form stable chlorides. A notable example is titanium(III) chloride (TiCl3), which is used as a catalyst for production of polyolefins (see Ziegler–Natta catalyst) and a reducing agent in organic chemistry.[52]
Organometallic complexes
Owing to the important role of titanium compounds as polymerization catalyst, compounds with Ti-C bonds have been intensively studied. The most common organotitanium complex is titanocene dichloride ((C5H5)2TiCl2). Related compounds include Tebbe's reagent and Petasis reagent. Titanium forms carbonyl complexes, e.g. (C5H5)2Ti(CO)2.[53]
Anticancer therapy studies
Following the success of platinum-based chemotherapy, titanium(IV) complexes were among the first non-platinum compounds to be tested for cancer treatment. The advantage of titanium compounds lies in their high efficacy and low toxicity in vivo.[54] In biological environments, hydrolysis leads to the safe and inert titanium dioxide. Despite these advantages the first candidate compounds failed clinical trials due to insufficient efficacy to toxicity ratios and formulation complications.[54] Further development resulted in the creation of potentially effective, selective, and stable titanium-based drugs.[54]
History
![Engraved profile image of a mid-age male with high forehead. The person is wearing a coat and a neckerchief.](https://upload.wikimedia.org/wikipedia/commons/thumb/c/cf/Martin_Heinrich_Klaproth.jpg/170px-Martin_Heinrich_Klaproth.jpg)
Titanium was discovered in 1791 by the clergyman and geologist William Gregor as an inclusion of a mineral in Cornwall, Great Britain.[55] Gregor recognized the presence of a new element in ilmenite[11] when he found black sand by a stream and noticed the sand was attracted by a magnet.[55] Analyzing the sand, he determined the presence of two metal oxides: iron oxide (explaining the attraction to the magnet) and 45.25% of a white metallic oxide he could not identify.[27] Realizing that the unidentified oxide contained a metal that did not match any known element, in 1791 Gregor reported his findings in both German and French science journals: Crell's Annalen and Observations et Mémoires sur la Physique.[55][56][57] He named this oxide manaccanite.[58]
Around the same time, Franz-Joseph Müller von Reichenstein produced a similar substance, but could not identify it.[11] The oxide was independently rediscovered in 1795 by Prussian chemist Martin Heinrich Klaproth in rutile from Boinik (the German name of Bajmócska), a village in Hungary (now Bojničky in Slovakia).[55][b] Klaproth found that it contained a new element and named it for the Titans of Greek mythology.[30] After hearing about Gregor's earlier discovery, he obtained a sample of manaccanite and confirmed that it contained titanium.[60]
The currently known processes for extracting titanium from its various ores are laborious and costly; it is not possible to reduce the ore by heating with carbon (as in iron smelting) because titanium combines with the carbon to produce titanium carbide.[55] Pure metallic titanium (99.9%) was first prepared in 1910 by Matthew A. Hunter at Rensselaer Polytechnic Institute by heating TiCl4 with sodium at 700–800 °C (1,292–1,472 °F) under great pressure[61] in a batch process known as the Hunter process.[10] Titanium metal was not used outside the laboratory until 1932 when William Justin Kroll produced it by reducing titanium tetrachloride (TiCl4) with calcium.[62] Eight years later he refined this process with magnesium and with sodium in what became known as the Kroll process.[62] Although research continues to seek cheaper and more efficient routes, such as the FFC Cambridge process, the Kroll process is still predominantly used for commercial production.[10][11]
![](https://upload.wikimedia.org/wikipedia/commons/thumb/5/5b/Titanium_metal.jpg/220px-Titanium_metal.jpg)
Titanium of very high purity was made in small quantities when Anton Eduard van Arkel and Jan Hendrik de Boer discovered the iodide process in 1925, by reacting with iodine and decomposing the formed vapors over a hot filament to pure metal.[63]
In the 1950s and 1960s, the Soviet Union pioneered the use of titanium in military and submarine applications[61] (Alfa class and Mike class)[64] as part of programs related to the Cold War.[65] Starting in the early 1950s, titanium came into use extensively in military aviation, particularly in high-performance jets, starting with aircraft such as the F-100 Super Sabre and Lockheed A-12 and SR-71.[66]
Throughout the Cold War period, titanium was considered a strategic material by the U.S. government, and a large stockpile of titanium sponge (a porous form of the pure metal) was maintained by the Defense National Stockpile Center, until the stockpile was dispersed in the 2000s.[67] As of 2021, the four leading producers of titanium sponge were China (52%), Japan (24%), Russia (16%) and Kazakhstan (7%).[28]
Production
![A small heap of uniform black grains smaller than 1mm diameter.](https://upload.wikimedia.org/wikipedia/commons/thumb/5/58/TitaniumUSGOV.jpg/220px-TitaniumUSGOV.jpg)
![](https://upload.wikimedia.org/wikipedia/commons/thumb/b/bf/Titanium_products.jpg/220px-Titanium_products.jpg)
Mineral beneficiation processes
- The Becher process is an industrial process used to produce synthetic rutile, a form of titanium dioxide, from the ore ilmenite.
- The Chloride process.
- The Sulfate process: "relies on sulfuric acid (H2SO4) to leach titanium from ilmenite ore (FeTiO3). The resulting reaction produces titanyl sulfate (TiOSO4). A secondary hydrolysis stage is used to break the titanyl sulfate into hydrated TiO2 and H2SO4. Finally, heat is used to remove the water and create the end product - pure TiO2."[68]
Purification processes
Hunter process
The Hunter process was the first industrial process to produce pure metallic titanium. It was invented in 1910 by Matthew A. Hunter, a chemist born in New Zealand who worked in the United States.[69] The process involves reducing titanium tetrachloride (TiCl4) with sodium (Na) in a batch reactor with an inert atmosphere at a temperature of 1,000 °C. Dilute hydrochloric acid is then used to leach the salt from the product.[70]
- TiCl4(g) + 4 Na(l) → 4 NaCl(l) + Ti(s)
Kroll process
The processing of titanium metal occurs in four major steps: reduction of titanium ore into "sponge", a porous form; melting of sponge, or sponge plus a master alloy to form an ingot; primary fabrication, where an ingot is converted into general mill products such as billet, bar, plate, sheet, strip, and tube; and secondary fabrication of finished shapes from mill products.[71]
Because it cannot be readily produced by reduction of titanium dioxide,[17] titanium metal is obtained by reduction of titanium tetrachloride (TiCl4) with magnesium metal in the Kroll process. The complexity of this batch production in the Kroll process explains the relatively high market value of titanium,[72] despite the Kroll process being less expensive than the Hunter process.[61] To produce the TiCl4 required by the Kroll process, the dioxide is subjected to carbothermic reduction in the presence of chlorine. In this process, the chlorine gas is passed over a red-hot mixture of rutile or ilmenite in the presence of carbon. After extensive purification by fractional distillation, the TiCl4 is reduced with 800 °C (1,470 °F) molten magnesium in an argon atmosphere.[15]
Arkel-Boer process
The van Arkel–de Boer process was the first semi-industrial process for pure Titanium. It involves thermal decomposition of titanium tetraiodide.
Armstrong process
Titanium powder is manufactured using a flow production process known as the Armstrong process[73] that is similar to the batch production Hunter process. A stream of titanium tetrachloride gas is added to a stream of molten sodium; the products (sodium chloride salt and titanium particles) is filtered from the extra sodium. Titanium is then separated from the salt by water washing. Both sodium and chlorine are recycled to produce and process more titanium tetrachloride.[74]
Pilot plants
Methods for electrolytic production of Ti metal from TiO2 using molten salt electrolytes have been researched and tested at laboratory and small pilot plant scales. The lead author of an impartial review published in 2017 considered his own process "ready for scaling up."[75] A 2023 review "discusses the electrochemical principles involved in the recovery of metals from aqueous solutions and fused salt electrolytes", with particular attention paid to titanium. While some metals such as nickel and copper can be refined by electrowinning at room temperature, titanium must be in the molten state and "there is a strong chance of attack of the refractory lining by molten titanium."[76] Zhang et al concluded their Perspective on Thermochemical and Electrochemical Processes for Titanium Metal Production in 2017 that "Even though there are strong interests in the industry for finding a better method to produce Ti metal, and a large number of new concepts and improvements have been investigated at the laboratory or even at pilot plant scales, there is no new process to date that can replace the Kroll process commercially."[77]
The Hydrogen assisted magnesiothermic reduction (HAMR) process uses titanium dihydride.
Fabrication
![](https://upload.wikimedia.org/wikipedia/commons/thumb/4/4b/Evolution_Ti.jpg/220px-Evolution_Ti.jpg)
All welding of titanium must be done in an inert atmosphere of argon or helium to shield it from contamination with atmospheric gases (oxygen, nitrogen, and hydrogen).[22] Contamination causes a variety of conditions, such as embrittlement, which reduce the integrity of the assembly welds and lead to joint failure.[78]
Titanium is very difficult to solder directly, and hence a solderable metal or alloy such as steel is coated on titanium prior to soldering.[79] Titanium metal can be machined with the same equipment and the same processes as stainless steel.[22]
Titanium alloys
Common titanium alloys are made by reduction. For example, cuprotitanium (rutile with copper added), ferrocarbon titanium (ilmenite reduced with coke in an electric furnace), and manganotitanium (rutile with manganese or manganese oxides) are reduced.[80]
About fifty grades of titanium alloys are designed and currently used, although only a couple of dozen are readily available commercially.[81] The ASTM International recognizes 31 grades of titanium metal and alloys, of which grades one through four are commercially pure (unalloyed). Those four vary in tensile strength as a function of oxygen content, with grade 1 being the most ductile (lowest tensile strength with an oxygen content of 0.18%), and grade 4 the least ductile (highest tensile strength with an oxygen content of 0.40%).[24] The remaining grades are alloys, each designed for specific properties of ductility, strength, hardness, electrical resistivity, creep resistance, specific corrosion resistance, and combinations thereof.[82]
In addition to the ASTM specifications, titanium alloys are also produced to meet aerospace and military specifications (SAE-AMS, MIL-T), ISO standards, and country-specific specifications, as well as proprietary end-user specifications for aerospace, military, medical, and industrial applications.[83]
Forming and forging
Commercially pure flat product (sheet, plate) can be formed readily, but processing must take into account of the tendency of the metal to springback. This is especially true of certain high-strength alloys.[84][85] Exposure to the oxygen in air at the elevated temperatures used in forging results in formation of a brittle oxygen-rich metallic surface layer called "alpha case" that worsens the fatigue properties, so it must be removed by milling, etching, or electrochemical treatment.[86] The working of titanium is very complicated,[87][88][89] and may include Friction welding,[90] cryo-forging,[91] and Vacuum arc remelting.
Applications
![](https://upload.wikimedia.org/wikipedia/commons/thumb/5/5b/Titanzylinder.jpg/220px-Titanzylinder.jpg)
Titanium is used in steel as an alloying element (ferro-titanium) to reduce grain size and as a deoxidizer, and in stainless steel to reduce carbon content.[9] Titanium is often alloyed with aluminium (to refine grain size), vanadium, copper (to harden), iron, manganese, molybdenum, and other metals.[92] Titanium mill products (sheet, plate, bar, wire, forgings, castings) find application in industrial, aerospace, recreational, and emerging markets. Powdered titanium is used in pyrotechnics as a source of bright-burning particles.[93]
Pigments, additives, and coatings
![Watch glass on a black surface with a small portion of white powder](https://upload.wikimedia.org/wikipedia/commons/thumb/a/a5/Titanium%28IV%29_oxide.jpg/220px-Titanium%28IV%29_oxide.jpg)
About 95% of all titanium ore is destined for refinement into titanium dioxide (TiO
2), an intensely white permanent pigment used in paints, paper, toothpaste, and plastics.[28] It is also used in cement, in gemstones, and as an optical opacifier in paper.[94]
TiO
2 pigment is chemically inert, resists fading in sunlight, and is very opaque: it imparts a pure and brilliant white color to the brown or grey chemicals that form the majority of household plastics.[11] In nature, this compound is found in the minerals anatase, brookite, and rutile.[9] Paint made with titanium dioxide does well in severe temperatures and marine environments.[11] Pure titanium dioxide has a very high index of refraction and an optical dispersion higher than diamond.[10] Titanium dioxide is used in sunscreens because it reflects and absorbs UV light.[17]
Aerospace and marine
![](https://upload.wikimedia.org/wikipedia/commons/thumb/0/04/A12-flying.jpg/220px-A12-flying.jpg)
Because titanium alloys have high tensile strength to density ratio,[15] high corrosion resistance,[10] fatigue resistance, high crack resistance,[95] and ability to withstand moderately high temperatures without creeping, they are used in aircraft, armor plating, naval ships, spacecraft, and missiles.[10][11] For these applications, titanium is alloyed with aluminium, zirconium, nickel,[96] vanadium, and other elements to manufacture a variety of components including critical structural parts, landing gear, firewalls, exhaust ducts (helicopters), and hydraulic systems. In fact, about two thirds of all titanium metal produced is used in aircraft engines and frames.[97] The titanium 6AL-4V alloy accounts for almost 50% of all alloys used in aircraft applications.[98]
The Lockheed A-12 and the SR-71 "Blackbird" were two of the first aircraft frames where titanium was used, paving the way for much wider use in modern military and commercial aircraft. A large amount of titanium mill products are used in the production of many aircraft, such as (following values are amount of raw mill products used, only a fraction of this ends up in the finished aircraft): 116 metric tons are used in the Boeing 787, 77 in the Airbus A380, 59 in the Boeing 777, 45 in the Boeing 747, 32 in the Airbus A340, 18 in the Boeing 737, 18 in the Airbus A330, and 12 in the Airbus A320.[99] In aero engine applications, titanium is used for rotors, compressor blades, hydraulic system components, and nacelles.[100][101] An early use in jet engines was for the Orenda Iroquois in the 1950s.[better source needed][102]
Because titanium is resistant to corrosion by sea water, it is used to make propeller shafts, rigging, heat exchangers in desalination plants,[10] heater-chillers for salt water aquariums, fishing line and leader, and divers' knives. Titanium is used in the housings and components of ocean-deployed surveillance and monitoring devices for science and military. The former Soviet Union developed techniques for making submarines with hulls of titanium alloys,[103] forging titanium in huge vacuum tubes.[96]
Industrial
![](https://upload.wikimedia.org/wikipedia/commons/thumb/5/5c/Titanium-stamps.jpg/220px-Titanium-stamps.jpg)
Welded titanium pipe and process equipment (heat exchangers, tanks, process vessels, valves) are used in the chemical and petrochemical industries primarily for corrosion resistance. Specific alloys are used in oil and gas downhole applications and nickel hydrometallurgy for their high strength (e. g.: titanium beta C alloy), corrosion resistance, or both. The pulp and paper industry uses titanium in process equipment exposed to corrosive media, such as sodium hypochlorite or wet chlorine gas (in the bleachery).[104] Other applications include ultrasonic welding, wave soldering,[105] and sputtering targets.[106]
Titanium tetrachloride (TiCl4), a colorless liquid, is important as an intermediate in the process of making TiO2 and is also used to produce the Ziegler–Natta catalyst. Titanium tetrachloride is also used to iridize glass and, because it fumes strongly in moist air, it is used to make smoke screens.[17]
Consumer and architectural
![](https://upload.wikimedia.org/wikipedia/commons/thumb/9/92/Tweeter_with_Titanium_membrane_of_loudspeaker_box_JBL_TI_5000%2C_1990s.jpg/220px-Tweeter_with_Titanium_membrane_of_loudspeaker_box_JBL_TI_5000%2C_1990s.jpg)
Titanium metal is used in automotive applications, particularly in automobile and motorcycle racing where low weight and high strength and rigidity are critical.[107](p 141) The metal is generally too expensive for the general consumer market, though some late model Corvettes have been manufactured with titanium exhausts,[108] and a Corvette Z06's LT4 supercharged engine uses lightweight, solid titanium intake valves for greater strength and resistance to heat.[109]
Titanium is used in many sporting goods: tennis rackets, golf clubs, lacrosse stick shafts; cricket, hockey, lacrosse, and football helmet grills, and bicycle frames and components. Although not a mainstream material for bicycle production, titanium bikes have been used by racing teams and adventure cyclists.[110]
Titanium alloys are used in spectacle frames that are rather expensive but highly durable, long lasting, light weight, and cause no skin allergies. Titanium is a common material for backpacking cookware and eating utensils. Though more expensive than traditional steel or aluminium alternatives, titanium products can be significantly lighter without compromising strength. Titanium horseshoes are preferred to steel by farriers because they are lighter and more durable.[111]
![](https://upload.wikimedia.org/wikipedia/commons/thumb/a/a1/El_Guggenheim_vizca%C3%ADno._%281454058701%29.jpg/220px-El_Guggenheim_vizca%C3%ADno._%281454058701%29.jpg)
Titanium has occasionally been used in architecture. The 42.5 m (139 ft) Monument to Yuri Gagarin, the first man to travel in space (55°42′29.7″N 37°34′57.2″E / 55.708250°N 37.582556°E), as well as the 110 m (360 ft) Monument to the Conquerors of Space on top of the Cosmonaut Museum in Moscow are made of titanium for the metal's attractive color and association with rocketry.[112][113] The Guggenheim Museum Bilbao and the Cerritos Millennium Library were the first buildings in Europe and North America, respectively, to be sheathed in titanium panels.[97] Titanium sheathing was used in the Frederic C. Hamilton Building in Denver, Colorado.[114]
Because of titanium's superior strength and light weight relative to other metals (steel, stainless steel, and aluminium), and because of recent advances in metalworking techniques, its use has become more widespread in the manufacture of firearms. Primary uses include pistol frames and revolver cylinders. For the same reasons, it is used in the body of some laptop computers (for example, in Apple's PowerBook G4).[115][116]
In 2023, Apple launched the iPhone 15 Pro, which uses a titanium enclosure.[117]
Some upmarket lightweight and corrosion-resistant tools, such as shovels, knife handles and flashlights, are made of titanium or titanium alloys.[116]
Jewelry
![](https://upload.wikimedia.org/wikipedia/commons/thumb/b/be/Anodized_titanium_table.jpg/220px-Anodized_titanium_table.jpg)
Because of its durability, titanium has become more popular for designer jewelry (particularly, titanium rings).[111] Its inertness makes it a good choice for those with allergies or those who will be wearing the jewelry in environments such as swimming pools. Titanium is also alloyed with gold to produce an alloy that can be marketed as 24-karat gold because the 1% of alloyed Ti is insufficient to require a lesser mark. The resulting alloy is roughly the hardness of 14-karat gold and is more durable than pure 24-karat gold.[118]
Titanium's durability, light weight, and dent and corrosion resistance make it useful for watch cases.[111] Some artists work with titanium to produce sculptures, decorative objects and furniture.[119]
Titanium may be anodized to vary the thickness of the surface oxide layer, causing optical interference fringes and a variety of bright colors.[120] With this coloration and chemical inertness, titanium is a popular metal for body piercing.[121]
Titanium has a minor use in dedicated non-circulating coins and medals. In 1999, Gibraltar released the world's first titanium coin for the millennium celebration.[122] The Gold Coast Titans, an Australian rugby league team, award a medal of pure titanium to their player of the year.[123]
Medical
Because titanium is biocompatible (non-toxic and not rejected by the body), it has many medical uses, including surgical implements and implants, such as hip balls and sockets (joint replacement) and dental implants that can stay in place for up to 20 years.[55] The titanium is often alloyed with about 4% aluminium or 6% Al and 4% vanadium.[124]
![](https://upload.wikimedia.org/wikipedia/commons/thumb/a/a0/Titanium_plaatje_voor_pols.jpg/220px-Titanium_plaatje_voor_pols.jpg)
Titanium has the inherent ability to osseointegrate, enabling use in dental implants that can last for over 30 years. This property is also useful for orthopedic implant applications.[55] These benefit from titanium's lower modulus of elasticity (Young's modulus) to more closely match that of the bone that such devices are intended to repair. As a result, skeletal loads are more evenly shared between bone and implant, leading to a lower incidence of bone degradation due to stress shielding and periprosthetic bone fractures, which occur at the boundaries of orthopedic implants. However, titanium alloys' stiffness is still more than twice that of bone, so adjacent bone bears a greatly reduced load and may deteriorate.[125][126]
Because titanium is non-ferromagnetic, patients with titanium implants can be safely examined with magnetic resonance imaging (convenient for long-term implants). Preparing titanium for implantation in the body involves subjecting it to a high-temperature plasma arc which removes the surface atoms, exposing fresh titanium that is instantly oxidized.[55]
Modern advancements in additive manufacturing techniques have increased potential for titanium use in orthopedic implant applications.[127] Complex implant scaffold designs can be 3D-printed using titanium alloys, which allows for more patient-specific applications and increased implant osseointegration.[128]
Titanium is used for the surgical instruments used in image-guided surgery, as well as wheelchairs, crutches, and any other products where high strength and low weight are desirable.[129]
Titanium dioxide nanoparticles are widely used in electronics and the delivery of pharmaceuticals and cosmetics.[130]
Nuclear waste storage
Because of its corrosion resistance, containers made of titanium have been studied for the long-term storage of nuclear waste. Containers lasting more than 100,000 years are thought possible with manufacturing conditions that minimize material defects.[131] A titanium "drip shield" could also be installed over containers of other types to enhance their longevity.[132]
Precautions
Titanium is non-toxic even in large doses and does not play any natural role inside the human body.[30] An estimated quantity of 0.8 milligrams of titanium is ingested by humans each day, but most passes through without being absorbed in the tissues.[30] It does, however, sometimes bio-accumulate in tissues that contain silica. One study indicates a possible connection between titanium and yellow nail syndrome.[133]
As a powder or in the form of metal shavings, titanium metal poses a significant fire hazard and, when heated in air, an explosion hazard.[134] Water and carbon dioxide are ineffective for extinguishing a titanium fire; Class D dry powder agents must be used instead.[11]
When used in the production or handling of chlorine, titanium should not be exposed to dry chlorine gas because it may result in a titanium–chlorine fire.[135]
Titanium can catch fire when a fresh, non-oxidized surface comes in contact with liquid oxygen.[136]
Function in plants
An unknown mechanism in plants may use titanium to stimulate the production of carbohydrates and encourage growth. This may explain why most plants contain about 1 part per million (ppm) of titanium, food plants have about 2 ppm, and horsetail and nettle contain up to 80 ppm.[30]
See also
Footnotes
- ^ The thermal expansion is anisotropic: the coefficients for each crystal axis are (at 20 °C): αa = 9.48×10−6/K, αc = 10.06×10−6/K, and αaverage = αV/3 = 9.68×10−6/K.
- ^
"Diesem zufolge will ich den Namen für die gegenwärtige metallische Substanz, gleichergestalt wie bei dem Uranium geschehen, aus der Mythologie, und zwar von den Ursöhnen der Erde, den Titanen, entlehnen, und benenne also diese neue Metallgeschlecht: Titanium; ... "[59](p 244)
References
- ^ "titanium". Lexico UK English Dictionary. Oxford University Press. Archived from the original on 20 December 2019.
- ^ "Standard Atomic Weights: Titanium". CIAAW. 1993.
- ^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (4 May 2022). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
- ^ a b Arblaster, John W. (2018). Selected Values of the Crystallographic Properties of Elements. Materials Park, Ohio: ASM International. ISBN 978-1-62708-155-9.
- ^ Jilek, Robert E.; Tripepi, Giovanna; Urnezius, Eugenijus; Brennessel, William W.; Young, Victor G. Jr.; Ellis, John E. (2007). "Zerovalent titanium–sulfur complexes. Novel dithiocarbamato derivatives of Ti(CO)6:[Ti(CO)4(S2CNR2)]−". Chem. Commun. (25): 2639–2641. doi:10.1039/B700808B. PMID 17579764.
- ^ Andersson, N.; et al. (2003). "Emission spectra of TiH and TiD near 938 nm" (PDF). J. Chem. Phys. 118 (8): 10543. Bibcode:2003JChPh.118.3543A. doi:10.1063/1.1539848.
- ^ Weast, Robert (1984). CRC, Handbook of Chemistry and Physics. Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4.
- ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
- ^ a b c d e f g h i "Titanium". Encyclopædia Britannica. 2006. Retrieved 19 January 2022.
- ^ a b c d e f g h i j k l m Lide, D. R., ed. (2005). CRC Handbook of Chemistry and Physics (86th ed.). Boca Raton (FL): CRC Press. ISBN 0-8493-0486-5.
- ^ a b c d e f g h i Krebs, Robert E. (2006). The History and Use of Our Earth's Chemical Elements: A Reference Guide (2nd ed.). Westport, CT: Greenwood Press. ISBN 978-0-313-33438-2.
- ^ Medical, Tokyo; University, Dental (24 May 2022). "Exploring what gives titanium implants their remarkable biocompatibility". Phys.org. Retrieved 2 May 2024.
- ^ Donachie 1988, p. 11
- ^ a b Barksdale 1968, p. 738
- ^ a b c d e f "Titanium". Columbia Encyclopedia (6th ed.). New York: Columbia University Press. 2000–2006. ISBN 978-0-7876-5015-5.
- ^ a b c Barbalace, Kenneth L. (2006). "Periodic Table of Elements: Ti – Titanium". Retrieved 26 December 2006.
- ^ a b c d e Stwertka, Albert (1998). "Titanium". Guide to the Elements (Revised ed.). Oxford University Press. pp. 81–82. ISBN 978-0-19-508083-4.
- ^ "Is Titanium A Refractory Metal". Special Metal Fabrication. 3 August 2021.
- ^ Steele, M. C.; Hein, R. A. (1953). "Superconductivity of Titanium". Phys. Rev. 92 (2): 243–247. Bibcode:1953PhRv...92..243S. doi:10.1103/PhysRev.92.243.
- ^ Thiemann, M.; et al. (2018). "Complete electrodynamics of a BCS superconductor with μeV energy scales: Microwave spectroscopy on titanium at mK temperatures". Phys. Rev. B. 97 (21): 214516. arXiv:1803.02736. Bibcode:2018PhRvB..97u4516T. doi:10.1103/PhysRevB.97.214516. S2CID 54891002.
- ^ Donachie 1988, Appendix J, Table J.2
- ^ a b c d e Barksdale 1968, p. 734
- ^ Puigdomenech, Ignasi (2004) Hydra/Medusa Chemical Equilibrium Database and Plotting Software, KTH Royal Institute of Technology.
- ^ a b c d e Emsley 2001, p. 453
- ^ Casillas, N.; Charlebois, S.; Smyrl, W.H.; White, H.S. (1994). "Pitting corrosion of titanium" (PDF). J. Electrochem. Soc. 141 (3): 636–642. Bibcode:1994JElS..141..636C. doi:10.1149/1.2054783. Archived (PDF) from the original on 27 August 2020.
- ^ Forrest, A.L. (1981). "Effects of Metal Chemistry on Behavior of Titanium in Industrial Applications". Industrial Applications of Titanium and Zirconium. p. 112.
- ^ a b c Barksdale 1968, p. 732
- ^ a b c d e "Titanium". USGS Minerals Information. United States Geological Survey (USGS).
- ^ Buettner, K. M.; Valentine, A. M. (2012). "Bioinorganic Chemistry of Titanium". Chemical Reviews. 112 (3): 1863–81. doi:10.1021/cr1002886. PMID 22074443.
- ^ a b c d e f Emsley 2001, p. 451
- ^ Titanium. Mindat
- ^ Wang, M.; Audi, G.; Kondev, F. G.; Huang, W. J.; Naimi, S.; Xu, X. (2017). "The AME2016 atomic mass evaluation (II). Tables, graphs, and references" (PDF). Chinese Physics C. 41 (3): 030003-1–030003-442. doi:10.1088/1674-1137/41/3/030003.
- ^ a b Greenwood & Earnshaw 1997, p. 958
- ^ Greenwood & Earnshaw 1997, p. 970
- ^ Greenwood & Earnshaw 1997, p. 960
- ^ Greenwood & Earnshaw 1997, p. 967
- ^ Greenwood & Earnshaw 1997, p. 961
- ^ Liu, Gang; Huang, Wan-Xia; Yi, Yong (26 June 2013). "Preparation and Optical Storage Properties of λTi3O5 Powder". Journal of Inorganic Materials. 28 (4): 425–430. doi:10.3724/SP.J.1077.2013.12309 (inactive 25 May 2024).
{{cite journal}}
: CS1 maint: DOI inactive as of May 2024 (link) - ^ Bonardi, Antonio; Pühlhofer, Gerd; Hermanutz, Stephan; Santangelo, Andrea (2014). "A new solution for mirror coating in γ-ray Cherenkov Astronomy". Experimental Astronomy. 38 (1–2): 1–9. arXiv:1406.0622. Bibcode:2014ExA....38....1B. doi:10.1007/s10686-014-9398-x. S2CID 119213226.
- ^ Greenwood & Earnshaw 1997, p. 962.
- ^ Ramón, Diego J.; Yus, Miguel (2006). "In the arena of enantioselective synthesis, titanium complexes wear the laurel wreath". Chem. Rev. 106 (6): 2126–2308. doi:10.1021/cr040698p. PMID 16771446.
- ^ McKelvy, M.J.; Glaunsinger, W.S. (1995). "Titanium Disulfide". Inorganic Syntheses. Vol. 30. pp. 28–32. doi:10.1002/9780470132616.ch7. ISBN 978-0-470-13261-6.
- ^ Saha, Naresh (1992). "Titanium nitride oxidation chemistry: An x-ray photoelectron spectroscopy study". Journal of Applied Physics. 72 (7): 3072–3079. Bibcode:1992JAP....72.3072S. doi:10.1063/1.351465.
- ^ Schubert, E.F. "The hardness scale introduced by Friederich Mohs" (PDF). Educational resources. Troy, NY: Rensselaer Polytechnic Institute. Archived (PDF) from the original on 3 June 2010.
- ^ Truini, Joseph (May 1988). "Drill bits". Popular Mechanics. Vol. 165, no. 5. p. 91. ISSN 0032-4558.
- ^ Baliga, B. Jayant (2005). Silicon carbide power devices. World Scientific. p. 91. ISBN 978-981-256-605-8.
- ^ "Titanium carbide product information". H.C. Starck. Archived from the original on 22 September 2017. Retrieved 16 November 2015.
- ^ Seong, S.; Younossi, O.; Goldsmith, B.W. (2009). Titanium: Industrial base, price trends, and technology initiatives (Report). Rand Corporation. p. 10. ISBN 978-0-8330-4575-1.
- ^ Johnson, Richard W. (1998). The Handbook of Fluid Dynamics. Springer. pp. 38–21. ISBN 978-3-540-64612-9.
- ^ Coates, Robert M.; Paquette, Leo A. (2000). Handbook of Reagents for Organic Synthesis. John Wiley and Sons. p. 93. ISBN 978-0-470-85625-3.
- ^ Greenwood & Earnshaw 1997, p. 965
- ^ Gundersen, Lise-Lotte; Rise, Frode; Undheim, Kjell; Méndez Andino, José (2007). "Titanium(III) Chloride". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rt120.pub2. ISBN 978-0-471-93623-7.
- ^ Hartwig, J.F. (2010). Organotransition Metal Chemistry, from Bonding to Catalysis. New York, NY: University Science Books. ISBN 978-1-891389-53-5.
- ^ a b c Tshuva, Edit Y.; Miller, Maya (2018). "Chapter 8. Coordination complexes of titanium(IV) for anticancer therapy". In Sigel, Astrid; Sigel, Helmut; Freisinger, Eva; Sigel, Roland K.O. (eds.). Metallo-drugs: Development and action of anticancer agents. Metal Ions in Life Sciences. Vol. 18. Berlin, DE: de Gruyter GmbH. pp. 219–250. doi:10.1515/9783110470734-014. ISBN 978-3-11-047073-4. PMID 29394027.
- ^ a b c d e f g h Emsley 2001, p. 452
- ^ Gregor, William (1791). "Beobachtungen und Versuche über den Menakanit, einen in Cornwall gefundenen magnetischen Sand" [Observations and experiments regarding menaccanite [i.e., ilmenite], a magnetic sand found in Cornwall]. Chemische Annalen (in German). 1: pp. 40–54, 103–119.
- ^ Gregor, William (1791). "Sur le menakanite, espèce de sable attirable par l'aimant, trouvé dans la province de Cornouilles" [On menaccanite, a species of magnetic sand, found in the county of Cornwall]. Observations et Mémoires sur la Physique (in French). 39: 72–78, 152–160.
- ^ Habashi, Fathi (January 2001). "Historical Introduction to Refractory Metals". Mineral Processing and Extractive Metallurgy Review. 22 (1): 25–53. Bibcode:2001MPEMR..22...25H. doi:10.1080/08827509808962488. S2CID 100370649.
- ^ Klaproth, Martin Heinrich (1795). "Chemische Untersuchung des sogenannten hungarischen rothen Schörls" [Chemical investigation of the so-called Hungarian red tourmaline [rutile]]. Beiträge zur chemischen Kenntniss der Mineralkörper [Contributions to the chemical knowledge of mineral substances]. 1. Berlin, DE: Heinrich August Rottmann: 233–244.
- ^ Twenty-five years of Titanium news: A concise and timely report on titanium and titanium recycling (Report). Suisman Titanium Corporation. 1995. p. 37 – via Pennsylvania State University / Google Books.
- ^ a b c Roza 2008, p. 9
- ^ a b Greenwood & Earnshaw 1997, p. 955
- ^ van Arkel, A.E.; de Boer, J.H. (1925). "Preparation of pure titanium, zirconium, hafnium, and thorium metal". Zeitschrift für anorganische und allgemeine Chemie. 148: 345–50. doi:10.1002/zaac.19251480133.
- ^ Yanko, Eugene (2006). "Submarines: General information". Omsk VTTV Arms Exhibition and Military Parade JSC. Archived from the original on 6 April 2016. Retrieved 2 February 2015.
- ^ "VSMPO stronger than ever" (PDF). Stainless Steel World. KCI Publishing B.V. July–August 2001. pp. 16–19. Archived from the original (PDF) on 5 October 2006. Retrieved 2 January 2007.
- ^ Jasper, Adam, ed. (2020). Architecture and Anthropology. Taylor & Francis. p. 42. ISBN 978-1-351-10627-6.
- ^ Defense National Stockpile Center (2008). Strategic and Critical Materials Report to the Congress. Operations under the Strategic and Critical Materials Stock Piling Act during the Period October 2007 through September 2008 (PDF) (Report). United States Department of Defense. p. 3304. Archived from the original (PDF) on 11 February 2010.
- ^ https://www.barbenanalytical.com/-/media/ametekbarbenanalytical/downloads/application_notes/tio2_an_reva.pdf?la=en&revision=eee43ea5-f5e3-4167-af19-4c177cc3dcdd.
{{cite news}}
: Missing or empty|title=
(help) - ^ M. A. Hunter "Metallic Titanium" J. Am. Chem. Soc. 1910, pp 330–336. doi:10.1021/ja01921a006
- ^ Schaschke, Carl (2014). "Hunter process". A Dictionary of Chemical Engineering. Oxford University Press. doi:10.1093/acref/9780199651450.001.0001. ISBN 978-0-19-965145-0.
- ^ Donachie 1988, Ch. 4
- ^ Barksdale 1968, p. 733
- ^ Roza 2008, p. 25
- ^ "Titanium". The Essential Chemical Industry online. CIEC Promoting Science. York, UK: University of York. 15 January 2015.
- ^ Fray, Derek; Schwandt, Carsten (2017). "Aspects of the Application of Electrochemistry to the Extraction of Titanium and Its Applications". Materials Transactions. 58 (3): 306–312. doi:10.2320/matertrans.MK201619. ISSN 1345-9678.
- ^ Shamsuddin, Mohammad; Sohn, Hong Yong (2023). "Role of electrochemical processes in the extraction of metals and alloys – a review". Mineral Processing and Extractive Metallurgy: Transactions of the Institutions of Mining and Metallurgy. 132 (3–4): 193–209. Bibcode:2023MPEM..132..193S. doi:10.1080/25726641.2023.2255368.
- ^ Zhang, Ying; Fang, Zhigang Zak; Sun, Pei; Zheng, Shili; Xia, Yang; Free, Michael (2017). "A Perspective on Thermochemical and Electrochemical Processes for Titanium Metal Production". JOM. 69 (10): 1861–1868. Bibcode:2017JOM....69j1861Z. doi:10.1007/s11837-017-2481-9.
- ^ Engel, Abraham L.; Huber, R.W.; Lane, I.R. (1955). Arc-welding Titanium. U.S. Department of the Interior, Bureau of Mines.
- ^ Lewis, W.J.; Faulkner, G.E.; Rieppel, P.J. (1956). Report on Brazing and Soldering of Titanium. Titanium Metallurgical Laboratory, Battelle Memorial Institute.
- ^ "Titanium". Microsoft Encarta. 2005. Archived from the original on 27 October 2006. Retrieved 29 December 2006.
- ^ Donachie 1988, p. 16, Appendix J
- ^ "Volume 02.04: Non-ferrous Metals". Annual Book of ASTM Standards. West Conshohocken, PA: ASTM International. 2006. section 2. ISBN 978-0-8031-4086-8. "Volume 13.01: Medical Devices; Emergency Medical Services". Annual Book of ASTM Standards. West Conshohocken, PA: ASTM International. 1998. sections 2 & 13. ISBN 978-0-8031-2452-3.
- ^ Donachie 1988, pp. 13–16, Appendices H and J
- ^ AWS G2.4/G2.4M:2007 Guide for the Fusion Welding of Titanium and Titanium Alloys. Miami: American Welding Society. 2006. Archived from the original on 10 December 2010.
- ^ Titanium design and fabrication handbook for industrial applications. Dallas: Titanium Metals Corporation. 1997. Archived from the original on 9 February 2009.
- ^ Chen, George Z.; Fray, Derek J.; Farthing, Tom W. (2001). "Cathodic deoxygenation of the alpha case on titanium and alloys in molten calcium chloride". Metall. Mater. Trans. B. 32 (6): 1041. doi:10.1007/s11663-001-0093-8. S2CID 95616531.
- ^ "Fabrication of Titanium and Titanium Alloys | Total Materia".
- ^ https://www.titaniuminfogroup.com/forging-process-of-titanium-alloy.html.
{{cite news}}
: Missing or empty|title=
(help) - ^ https://www.aubertduval.com/wp-media/uploads/2021/06/brochure-titane_2021.pdf.
{{cite news}}
: Missing or empty|title=
(help) - ^ "Linear Friction Welding: A Solution for Titanium Forgings".
- ^ "Ultra-Cold Forging Makes Titanium Strong and Ductile". 21 October 2021.
- ^ Hampel, Clifford A. (1968). The Encyclopedia of the Chemical Elements. Van Nostrand Reinhold. p. 738. ISBN 978-0-442-15598-8.
- ^ Mocella, Chris; Conkling, John A. (2019). Chemistry of Pyrotechnics. CRC Press. p. 86. ISBN 978-1-351-62656-9.
- ^ Smook, Gary A. (2002). Handbook for Pulp & Paper Technologists (3rd ed.). Angus Wilde Publications. p. 223. ISBN 978-0-9694628-5-9.
- ^ Moiseyev, Valentin N. (2006). Titanium Alloys: Russian Aircraft and Aerospace Applications. Taylor and Francis, LLC. p. 196. ISBN 978-0-8493-3273-9.
- ^ a b Kramer, Andrew E. (5 July 2013). "Titanium Fills Vital Role for Boeing and Russia". The New York Times. Retrieved 6 July 2013.
- ^ a b Emsley 2001, p. 454
- ^ Donachie 1988, p. 13
- ^ Froes, F.H., ed. (2015). Titanium Physical Metallurgy, Processing, and Applications. ASM International. p. 7. ISBN 978-1-62708-080-4.
- ^ "Titanium in Aerospace – Titanium". 10 April 2024. Retrieved 8 May 2024.
- ^ "Titanium Metal (Ti) / Sponge / Titanium Powder" (PDF). www.lb7.uscourts.gov. Retrieved 8 May 2024.
- ^ "Iroquois". Flight Global (archive). 1957. p. 412. Archived from the original on 13 December 2009.
- ^ "Unravelling a Cold War Mystery" (PDF). CIA. 2007. Retrieved 8 May 2024.
- ^ Donachie 1988, pp. 11–16
- ^ Kleefisch, E.W., ed. (1981). Industrial Application of Titanium and Zirconium. West Conshohocken, PA: ASTM International. ISBN 978-0-8031-0745-8.
- ^ Bunshah, Rointan F., ed. (2001). "chapter 8". Handbook of Hard Coatings. Norwich, NY: William Andrew Inc. ISBN 978-0-8155-1438-1.
- ^ Funatani, K. (9–12 October 2000). "Recent trends in surface modification of light metals § Metal matrix composite technologies". In Funatani, Kiyoshi; Totten, George E. (eds.). Heat Treating, an International ... Symposium on Residual Stresses in the Heat Treatment Industry. 20th ASM Heat Treating Society Conference. Vol. 1 & 2. St. Louis, MO: ASM International (published 2001). pp. 138–144, esp. 141. ISBN 978-0-87170-727-7.
- ^ "Titanium exhausts". National Corvette Museum. 2006. Archived from the original on 3 January 2013. Retrieved 26 December 2006.
- ^ "Compact powerhouse: Inside Corvette Z06's LT4 engine 650-hp supercharged 6.2L V-8 makes world-class power in more efficient package". media.gm.com (Press release). General Motors. 20 August 2014.
- ^ Davis, Joseph R. (1998). Metals Handbook. ASM International. p. 584. ISBN 978-0-87170-654-6 – via Internet Archive (archive.org).
- ^ a b c Donachie 1988, pp. 11, 255
- ^ Mike Gruntman (2004). Blazing the Trail: The Early History of Spacecraft and Rocketry. Reston, VA: American Institute of Aeronautics and Astronautics. p. 457. ISBN 978-1-56347-705-8.
- ^ Lütjering, Gerd; Williams, James Case (12 June 2007). "Appearance Related Applications". Titanium. Springer. ISBN 978-3-540-71397-5.
- ^ "Denver Art Museum, Frederic C. Hamilton Building". SPG Media. 2006. Retrieved 26 December 2006.
- ^ "Apple PowerBook G4 400 (Original – Ti) Specs". everymac.com. Retrieved 8 August 2009.
- ^ a b Qian, Ma; Niinomi, Mitsuo (2019). Real-World Use of Titanium. Elsevier Science. pp. 7–8. ISBN 978-0-12-815820-3.
- ^ "Apple Announces iPhone 15 Pro Models With Titanium Enclosure". CNET. Retrieved 19 September 2023.
- ^ Gafner, G. (1989). "The development of 990 Gold-Titanium: its Production, use and Properties" (PDF). Gold Bulletin. 22 (4): 112–122. doi:10.1007/BF03214709. S2CID 114336550. Archived from the original (PDF) on 29 November 2010.
- ^ "Fine Art and Functional Works in Titanium and Other Earth Elements". Archived from the original on 13 May 2008. Retrieved 8 August 2009.
- ^ Alwitt, Robert S. (2002). "Electrochemistry Encyclopedia". Chemical Engineering Department, Case Western Reserve University, U.S. Archived from the original on 2 July 2008. Retrieved 30 December 2006.
- ^ "Body Piercing Safety". doctorgoodskin.com. 1 August 2006.
- ^ "World Firsts". British Pobjoy Mint. Archived from the original on 26 February 2015. Retrieved 11 November 2017.
- ^ Turgeon, Luke (20 September 2007). "Titanium Titan: Broughton immortalised". The Gold Coast Bulletin. Archived from the original on 28 September 2013.
- ^ "Orthopaedic Metal Alloys". Totaljoints.info. Retrieved 27 September 2010.
- ^ "Titanium foams replace injured bones". Research News. 1 September 2010. Archived from the original on 4 September 2010. Retrieved 27 September 2010.
- ^ Lavine, Marc S. (11 January 2018). Vignieri, Sacha; Smith, Jesse (eds.). "Make no bones about titanium". Science. 359 (6372): 173.6–174. Bibcode:2018Sci...359..173L. doi:10.1126/science.359.6372.173-f.
- ^ Harun, W.S.W.; Manam, N.S.; Kamariah, M.S.I.N.; Sharif, S.; Zulkifly, A.H.; Ahmad, I.; Miura, H. (2018). "A review of powdered additive manufacturing techniques for Ti-6al-4v biomedical applications" (PDF). Powder Technology. 331: 74–97. doi:10.1016/j.powtec.2018.03.010.
- ^ Trevisan, Francesco; Calignano, Flaviana; Aversa, Alberta; Marchese, Giulio; Lombardi, Mariangela; Biamino, Sara; Ugues, Daniele; Manfredi, Diego (2017). "Additive manufacturing of titanium alloys in the biomedical field: processes, properties and applications". Journal of Applied Biomaterials & Functional Materials. 16 (2): 57–67. doi:10.5301/jabfm.5000371. PMID 28967051. S2CID 27827821.
- ^ Qian, Ma; Niinomi, Mitsuo (2019). Real-World Use of Titanium. Elsevier Science. pp. 51, 128. ISBN 978-0-12-815820-3.
- ^ Pinsino, Annalisa; Russo, Roberta; Bonaventura, Rosa; Brunelli, Andrea; Marcomini, Antonio; Matranga, Valeria (28 September 2015). "Titanium dioxide nanoparticles stimulate sea urchin immune cell phagocytic activity involving TLR/p38 MAPK-mediated signalling pathway". Scientific Reports. 5: 14492. Bibcode:2015NatSR...514492P. doi:10.1038/srep14492. PMC 4585977. PMID 26412401.
- ^ Shoesmith, D. W.; Noel, J. J.; Hardie, D.; Ikeda, B. M. (2000). "Hydrogen Absorption and the Lifetime Performance of Titanium Nuclear Waste Containers". Corrosion Reviews. 18 (4–5): 331–360. doi:10.1515/CORRREV.2000.18.4-5.331. S2CID 137825823.
- ^ Carter, L.J.; Pigford, T.J. (2005). "Proof of Safety at Yucca Mountain". Science. 310 (5747): 447–448. doi:10.1126/science.1112786. PMID 16239463. S2CID 128447596.
- ^ Berglund, Fredrik; Carlmark, Bjorn (October 2011). "Titanium, Sinusitis, and the Yellow Nail Syndrome". Biological Trace Element Research. 143 (1): 1–7. Bibcode:2011BTER..143....1B. doi:10.1007/s12011-010-8828-5. PMC 3176400. PMID 20809268.
- ^ Cotell, Catherine Mary; Sprague, J.A.; Smidt, F.A. (1994). ASM Handbook: Surface Engineering (10th ed.). ASM International. p. 836. ISBN 978-0-87170-384-2.
- ^ Compressed Gas Association (1999). Handbook of compressed gases (4th ed.). Springer. p. 323. ISBN 978-0-412-78230-5.
- ^ Solomon, Robert E. (2002). Fire and Life Safety Inspection Manual. National Fire Prevention Association (8th ed.). Jones & Bartlett Publishers. p. 45. ISBN 978-0-87765-472-8.
Bibliography
- Barksdale, Jelks (1968). "Titanium". In Clifford A. Hampel (ed.). The Encyclopedia of the Chemical Elements. New York, NY: Reinhold Book Corporation. pp. 732–738. LCCN 68029938.
- Donachie, Matthew J. Jr. (1988). Titanium: A technical guide. Metals Park, OH: ASM International. p. 11. ISBN 978-0-87170-309-5.
- Emsley, John (2001). "Titanium". Nature's Building Blocks: An A-Z guide to the elements. Oxford, England, UK: Oxford University Press. ISBN 978-0-19-850340-8.
- Flower, Harvey M. (2000). "Materials Science: A moving oxygen story". Nature. 407 (6802): 305–306. doi:10.1038/35030266. PMID 11014169. S2CID 4425634.
- Greenwood, N. N.; Earnshaw, A. (1997). Chemistry of the Elements (2nd ed.). Oxford: Butterworth-Heinemann. ISBN 978-0-7506-3365-9.
- Roza, Greg (2008). Titanium (1st ed.). New York, NY: The Rosen Publishing Group. ISBN 978-1-4042-1412-5.
External links
- "Titanium: Our Next Major Metal" in Popular Science (October 1950), one of first general public detailed articles on Titanium
- Titanium at Periodic Videos (University of Nottingham)
- Titanium.org: official website of the International Titanium Association, an industry association
- Metallurgy of Titanium and its Alloys - slide presentations, movies, and other material from Harshad Bhadeshia and other Cambridge University metallurgists