Cannabaceae

Sulfonmethane
Clinical data
ATC code
  • none
Legal status
Legal status
Identifiers
  • 2,2-bis(ethylsulfonyl)propane
CAS Number
PubChem CID
ChemSpider
UNII
CompTox Dashboard (EPA)
ECHA InfoCard100.003.704 Edit this at Wikidata
Chemical and physical data
FormulaC7H16O4S2
Molar mass228.32 g·mol−1
3D model (JSmol)
  • O=S(=O)(C(C)(C)S(=O)(=O)CC)CC
  • InChI=1S/C7H16O4S2/c1-5-12(8,9)7(3,4)13(10,11)6-2/h5-6H2,1-4H3 checkY
  • Key:CESKLHVYGRFMFP-UHFFFAOYSA-N checkY
 ☒NcheckY (what is this?)  (verify)

Sulfonmethane (sulfonomethane, sulfonal, acetone diethyl sulfone)[1] is a chemical compound first synthesized by Eugen Baumann in 1888 and introduced as a hypnotic drug by Alfred Kast later on, but now superseded by newer and safer sedatives.[2] Its appearance is either in colorless crystalline or powdered form. In United States, it is scheduled as a Schedule III drug in the Controlled Substance Act.[3]

Chemistry

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Sulfonal is prepared by condensing acetone with ethyl mercaptan in the presence of hydrochloric acid, the mercaptol (CH3)2C(SC2H5)2 formed being subsequently oxidized by potassium permanganate. It is also formed by the action of alcoholic potash and methyl iodide on ethylidene diethyl sulfine, CH3CH(SO2C2H5)2 (which is formed by the oxidation of dithioacetal with potassium permanganate). It crystallizes in prisms melting at 125 C, which are practically insoluble in cold water, but dissolves in 15 parts of hot water and also in alcohol and ether.

See also

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References

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Further reading

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  • Kast A (1888). Sulfonal, ein neues Schlafmittel (in German). Berlin.{{cite book}}: CS1 maint: location missing publisher (link)
  • Wendt EC (1888). "Sulfonal, a new Hypnotic". The Medical Record. 33 (22). New York: 597–598.
  • Bayer (1889). "Sulfonal". The Cincinnati Lancet-Clinic. 22. Cincinnati: J. C. Culbertson: 2.

One thought on “Cannabaceae

  1. Well, that’s interesting to know that Psilotum nudum are known as whisk ferns. Psilotum nudum is the commoner species of the two. While the P. flaccidum is a rare species and is found in the tropical islands. Both the species are usually epiphytic in habit and grow upon tree ferns. These species may also be terrestrial and grow in humus or in the crevices of the rocks.
    View the detailed Guide of Psilotum nudum: Detailed Study Of Psilotum Nudum (Whisk Fern), Classification, Anatomy, Reproduction

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