Intermolecular asymmetric functionalization of unstrained C(sp3)–C(sp3) bonds in allylic substitution reactions YW Chen, Y Qiu, Y Liu, GQ Lin, JF Hartwig, ZT He Nature Synthesis, 1-10, 2024 | | 2024 |
Copper-Mediated Cyanodifluoromethylation of (Hetero)aryl Iodides and Activated (Hetero)aryl Bromides with TMSCF2CN J Nicolai, T Fantoni, TW Butcher, S Arlow, SV Ryabukhin, DM Volochnyuk, ... Journal of the American Chemical Society, 2024 | | 2024 |
Polymers from Plant Oils Linked by Siloxane Bonds for Programmed Depolymerization C Cheng, JX Shi, EH Kang, TF Nelson, M Sander, K McNeill, JF Hartwig Journal of the American Chemical Society 146 (18), 12645-12655, 2024 | | 2024 |
Deconvolution and Analysis of the 1H NMR Spectra of Crude Reaction Mixtures MC Venetos, M Elkin, C Delaney, JF Hartwig, KA Persson Journal of Chemical Information and Modeling 64 (8), 3008-3020, 2024 | | 2024 |
2-Aminophenanthroline Ligands Enable Mild, Undirected, Iridium-Catalyzed Borylation of Alkyl C–H Bonds IF Yu, KA D’Angelo, ÁD Hernandez-Mejías, N Cheng, JF Hartwig Journal of the American Chemical Society 146 (11), 7124-7129, 2024 | 2 | 2024 |
Mechanistic insights into the origins of selectivity in a Cu-catalyzed C–H amidation reaction AJ Sterling, NR Ciccia, Y Guo, JF Hartwig, M Head-Gordon Journal of the American Chemical Society 146 (9), 6168-6177, 2024 | 1 | 2024 |
Mapping the mechanisms of oxidative addition in cross-coupling reactions catalysed by phosphine-ligated Ni (0) CN Pierson, JF Hartwig Nature Chemistry, 1-8, 2024 | 1 | 2024 |
Enantio-and Diastereodivergent Cyclopropanation of Allenes by Directed Evolution of an Iridium-Containing Cytochrome BJ Bloomer, IA Joyner, M Garcia-Borràs, DB Hu, M Garçon, A Quest, ... Journal of the American Chemical Society 146 (3), 1819-1824, 2024 | | 2024 |
2-Aminophenanthrolines Enable the Mild, Undirected Borylation of Alkyl C–H Bonds I Yu, K D'Angelo, Á Hernandez-Mejías, N Cheng, J Hartwig | | 2023 |
Diverse functional polyethylenes by catalytic amination NR Ciccia, JX Shi, S Pal, M Hua, KG Malollari, C Lizandara-Pueyo, ... Science 381 (6665), 1433-1440, 2023 | 10 | 2023 |
Transition-Metal-Catalyzed Silylation and Borylation of C–H Bonds for the Synthesis and Functionalization of Complex Molecules IF Yu, JW Wilson, JF Hartwig Chemical Reviews 123 (19), 11619-11663, 2023 | 23 | 2023 |
Chemical Modification of Oxidized Polyethylene Enables Access to Functional Polyethylenes with Greater Reuse JX Shi, NR Ciccia, S Pal, DD Kim, JN Brunn, C Lizandara-Pueyo, M Ernst, ... Journal of the American Chemical Society 145 (39), 21527-21537, 2023 | 9 | 2023 |
Transition-State Stabilization by Secondary Orbital Interactions between Fluoroalkyl Ligands and Palladium During Reductive Elimination from Palladium (aryl)(fluoroalkyl) Complexes ED Kalkman, Y Qiu, JF Hartwig ACS Catalysis 13 (19), 12810-12825, 2023 | 2 | 2023 |
Cross-coupling by a noncanonical mechanism involving the addition of aryl halide to Cu (II) CP Delaney, E Lin, Q Huang, IF Yu, G Rao, L Tao, A Jed, SM Fantasia, ... Science 381 (6662), 1079-1085, 2023 | 13 | 2023 |
Oxidative addition of an alkyl halide to form a stable Cu (III) product Y Luo, Y Li, J Wu, XS Xue, JF Hartwig, Q Shen Science 381 (6662), 1072-1079, 2023 | 24 | 2023 |
Iridium-Catalyzed, Site-Selective Silylation of Secondary C(sp3)–H Bonds in Secondary Alcohols and Ketones JW Wilson, B Su, M Yoritate, JX Shi, JF Hartwig Journal of the American Chemical Society 145 (36), 19490-19495, 2023 | 3 | 2023 |
Hybrid machine learning approach to predict the site selectivity of iridium-catalyzed arene borylation E Caldeweyher, M Elkin, G Gheibi, M Johansson, C Sköld, PO Norrby, ... Journal of the American Chemical Society 145 (31), 17367-17376, 2023 | 15 | 2023 |
Discovery of the Azaserine Biosynthetic Pathway Uncovers a Biological Route for α‐Diazoester Production D Van Cura, TL Ng, J Huang, H Hager, JF Hartwig, JD Keasling, ... Angewandte Chemie International Edition 62 (28), e202304646, 2023 | 11 | 2023 |
Progression of Hydroamination Catalyzed by Late Transition-Metal Complexes from Activated to Unactivated Alkenes S Ma, JF Hartwig Accounts of Chemical Research 56 (12), 1565-1577, 2023 | 19 | 2023 |
Complete integration of carbene-transfer chemistry into biosynthesis J Huang, A Quest, P Cruz-Morales, K Deng, JH Pereira, D Van Cura, ... Nature 617 (7960), 403-408, 2023 | 16 | 2023 |